It seems you need some kind of post-synthesis timing simulation to achieve jitter effects, don't you?
He's right. Is more useful to run these kind of test after synthesis and not too useful before synthesis. If you run post synthesis, you work with all physical events such as std cell timings, power analysis, etc. If you have a valid concern to simulate jitter before synthesis, then I believe you could play with inter and intra delays in your hdl model first.